On the versatile and unusual coordination behavior of ambiphilic ligands o-R2P(Ph)BR′2
On the versatile and unusual coordination behavior of ambiphilic ligands o-R2P(Ph)BR′2
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DOI：
10.1021/ja0637494
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发表时间：
2006-09-20
影响因子：
15
通讯作者：
Bourissou, Didier
中科院分区：
文献类型：
--
作者：
Bontemps, Sebastien;Bouhadir, Ghenwa;Bourissou, Didier
单膦-硼烷表现为双齿两亲性配体，其结构的多样性已经通过制备PdII和AuI络合物来说明，该络合物分别具有不寻常的P → M−Cl → B和P → M → B相互作用。
Monophosphine−boranes were shown to behave as bidentate ambiphilic ligands, whose structural versatility has been illustrated by the preparation of PdIIand AuIcomplexes featuring unusual P → M−Cl → B and P → M → B interactions, respectively.