On-site Raman analysis of Medici porcelain
On-site Raman analysis of Medici porcelain
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DOI：
10.1002/jrs.1085
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发表时间：
2004-01-01
影响因子：
2.5
通讯作者：
Lucas, H
中科院分区：
文献类型：
--
作者：
Colomban, P;Milande, V;Lucas, H
现场拉曼分析是在法国塞夫勒国家陶瓷博物馆进行的，对稀有的、最早为人所知的欧洲瓷盘进行了分析，这些瓷盘于1575年至1587年在佛罗伦萨生产，由大杜克弗朗西斯科一世德美第奇赞助。根据以前的化学分析结果进行了讨论。不同的识别相是a-石英，长石，磷酸钙和β-（和α-）硅灰石，即硬瓷和软瓷的指纹。长石的存在与钾和铝的高含量相一致，这从先前的成分分析中显而易见。石英颗粒的良好溶解和β-硅灰石（CaSiO 3）的特征与玻璃器皿技术一致。牙釉质中的磷酸钙表明使用了伊斯兰的煅烧骨乳浊技术。版权所有（C）2003约翰威利父子有限公司。
On-site Raman analyses were performed at the Musee National de Ceramique, Sevres, France, on the rare, first-known European porcelain dishes, produced from 1575 to 1587 in Florence, under the patronage of Grand Duke Francesco I de Medici. The results are discussed in the light of previous chemical analyses. The different identified phases are a-quartz, feldspar, calcium phosphate and beta-(and alpha-) wollastonite, i.e. the fingerprints of both hard- and soft-paste porcelains. The presence of feldspar is consistent with the high potassium and aluminium content, evident from previous composition analysis. The good dissolution of quartz grains and the signature of beta-wollastonite (CaSiO3) are consistent with a frit-ware technology. Calcium phosphate in the enamel indicates that the Islamic technique of opacification with calcined bone was used. Copyright (C) 2003 John Wiley Sons, Ltd.