Stochastic models for chemical reactions: I. Theory of the unimolecular reaction process
Stochastic models for chemical reactions: I. Theory of the unimolecular reaction process
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化学反应的随机模型：一、单分子反应过程理论
DOI：
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发表时间：
1958
期刊：
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通讯作者：
A. Bartholomay
中科院分区：
文献类型：
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作者：
A. Bartholomay
基本单分子化学反应的随机模型（Amathop o极限（μ B）。这个模型提供了一个数学基础，完全丢失在目前的动力学理论，分析固有的随机波动的严格浓度的时间过程中规定的现有的确定性理论。获得预测的固有变异性的程度上的限制，并与那些通常预期纯粹的基础上的随机实验误差无关的起源（不相关的反应机制）。这些结果支持了E.薛定谔的“（sqrt n）物理定律”。
A stochastic model for the basic unimolecular chemical reaction(Amathop o limits^mu B) is derived. This model provides a mathematical basis, altogether missing in the current kinetic theory, for the analysis of inherent random fluctuations about the strict concentration-time course prescribed by the existing deterministic theory. Limits on the extent of the predicted inherent variability are obtained and compared with those usually expected purely on the basis of random experimental errors of extraneous origin (not associated with the mechanism of reaction). The results support the extrapolation to chemical systems of a principle of statistical inaccuracy for physical systems which has been called by E. Schroedinger “the(sqrt n ) Law of Physics.”