The Effects of Temperature and Inorganic Salts on the Aqueous Solubility of Selected Chlorobenzenes
The Effects of Temperature and Inorganic Salts on the Aqueous Solubility of Selected Chlorobenzenes
复制标题
温度和无机盐对选定氯苯的水溶性的影响
DOI：
10.1021/je034170d
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发表时间：
2004
影响因子：
--
通讯作者：
Takashi Nakamura
中科院分区：
文献类型：
--
作者：
Sylwia Oleszek;E. Shibata;Takashi Nakamura
本文报道的实验结果是更广泛的研究计划中的第一个，旨在在实验室中测试选定的疏水化合物在水性系统中的行为。采用发生器柱法测定 25 °C 下联苯、1,2-二氯苯 (1,2-DCBz) 和六氯苯 (HxCBz) 在水中的溶解度。 1,2-DCBz 和 HxCBz 的溶解度在 15 至 55 °C 的温度范围内测量，溶液的热函来自 van't Hoff 图。在 25 °C 下测定了三种电解质对 HxCBz 溶解度的影响，并报告了它们新获得的 Setschenow 常数。
The experimental results reported in this paper are the first in a wider research program aiming to test, in a laboratory, the behavior of selected hydrophobic compounds in an aqueous system. The generator column method was used to determine the solubility in water of biphenyl, 1,2-dichlorobenzene (1,2-DCBz), and hexachlorobenzene (HxCBz) at 25 °C. The solubilities of 1,2-DCBz and HxCBz were measured at temperatures ranging from 15 to 55 °C, and the enthalpies of solutions were derived from van't Hoff plots. The effects of three electrolytes on the solubility of HxCBz were determined at 25 °C, and their newly obtained Setschenow constants are reported.
非邻位和单邻位 PCB 在四种温度下的水溶解度。
影响因子：
12.8
作者：
Huang,Qingdong;Hong,Chia-Swee
通讯作者：
Hong,Chia-Swee