Design and synthesis of low band gap non-fullerene acceptors for organic solar cells with impressively high Jsc over 21 mA cm-2

Design and synthesis of low band gap non-fullerene acceptors for organic solar cells with impressively high Jsc over 21 mA cm-2
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用于有机太阳能电池的低带隙非富勒烯受体的设计和合成,其 Jsc 超过 21 mA cm –2

DOI:
10.1007/s40843-017-9084-x
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发表时间:
2017-09-01
影响因子:
8.1
通讯作者:
Chen, Yongsheng
Chen, Yongsheng
中科院分区:
材料科学2区
文献类型:
--
作者:
Gao, Huan-Huan;Sun, Yanna;Chen, Yongsheng

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设计并合成了三种不同端基的噻吩并[3,2-B]噻吩类低能带隙非富勒烯受体化合物TTIC-M、TTIC和TTIC-F。以宽带隙聚合物PBDB-T为施主,在300-900 nm范围内形成互补吸收,TTIC-M、TTIC和TTFC-F基光伏器件的光电转换效率分别达到9.97%、10.87%和9.51%,短路电流超过21 mA·cm ~(-2)。
Three low bandgap non-fullerene acceptors based on thieno[3,2-b] thiophene fused core with different ending groups, named TTIC-M, TTIC, TTIC-F were designed and synthesized. Using a wide bandgap polymer PBDB-T as donor to form a complementary absorption in the range of 300-900 nm, high efficencies of 9.97%, 10.87% and 9.51% were achieved for TTIC-M, TTIC and TTFC-F based photovoltaic devices with impressively high short circuit current over 21 mA cm(-2).