Synthesis of all four possible stereoisomers of 5,9-dimethylpentadecane, the major sex pheromone component of the coffee leaf miner moth, Perileucoptera coffeella

Synthesis of all four possible stereoisomers of 5,9-dimethylpentadecane, the major sex pheromone component of the coffee leaf miner moth, Perileucoptera coffeella
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DOI:
10.1271/bbb.64.2723
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发表时间:
2000-12-01
影响因子:
1.6
通讯作者:
Kodama, O
Kodama, O
中科院分区:
工程技术4区
文献类型:
--
作者:
Kuwahara, S;Liang, T;Kodama, O

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以(S)-和(R)-3-羟基-2-甲基丙酸甲酯为手性来源,合成了咖啡叶潜蛾(Peuileucoptera Cofeella)的主要性信息素组分5,9-二甲基十五烷的4种可能的立体异构体,以确定信息素的立体化学。
All of the four possible stereoisomers of 5,9-dimethylpentadecane, the major sex pheromone component of the coffee leaf miner moth (Peuileucoptera cofeella), were synthesized by using the methyl esters of (S)- and (R)-3-hydroxy-2-methylpropanoic acid as chiral sources for the purpose of determining the stereochemistry of the pheromone.