One stone two birds: construction of polysubstituted benzenes from the same starting material and precatalyst by switching the active sites of catalyst with different additives.
One stone two birds: construction of polysubstituted benzenes from the same starting material and precatalyst by switching the active sites of catalyst with different additives.
复制标题
DOI：
10.1039/c1cc15835j
复制
发表时间：
2012-01
影响因子：
4.9
通讯作者：
C. Feng;Xin Wang;Bi-qin Wang;K. Zhao;P. Hu;Zhangjie Shi
中科院分区：
文献类型：
--
作者：
C. Feng;Xin Wang;Bi-qin Wang;K. Zhao;P. Hu;Zhangjie Shi
通过以 CuI 或 AgOTf 作为添加剂调整 Grubbs 第二代催化剂 (GC-II) 的活性位点，从相同的起始材料选择性地构建了两种不同的四取代苯。
Two different tetrasubstituted benzenes were selectively constructed from the same starting materials by tuning the active sites of the Grubbs second generation catalyst (GC-II) with CuI or AgOTf as the additive.