Ruthenium complex immobilized on mesoporous silica as recyclable heterogeneous catalyst for visible light photocatalysis

Ruthenium complex immobilized on mesoporous silica as recyclable heterogeneous catalyst for visible light photocatalysis
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DOI:
10.1007/s40242-014-3367-9
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发表时间:
2014-01
影响因子:
3.1
通讯作者:
He Hongyan;L. Wenliang;Xie Zhigang;Jing Xiabin;Hu Yubin
He Hongyan;L. Wenliang;Xie Zhigang;Jing Xiabin;Hu Yubin
中科院分区:
化学3区
文献类型:
--
作者:
He Hongyan;L. Wenliang;Xie Zhigang;Jing Xiabin;Hu Yubin

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Aldehyde group-functionalized [Ru(bpy)2L](PF6)2catalyst was prepared and immobilized onto the mesoporous silica nanoparticles to act as a heterogeneous catalyst for the selective oxidation of thioanisole to methyl phenyl sulfoxide under visible light. The heterogeneous catalyst can be easily recovered by simple centrifugation without chemical treatment, exhibiting comparable catalytic efficiency with homogeneous ones and no decrease in catalytic efficiency after at least 5 cycles.