Synthesis and structure of the first donor-stabilized bis(silylene)manganese complex
Synthesis and structure of the first donor-stabilized bis(silylene)manganese complex
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第一个供体稳定的双(亚硅基)锰配合物的合成和结构
DOI:
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发表时间:
1991
期刊:
影响因子:
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通讯作者:
H. Ogino
中科院分区:
文献类型:
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作者:
Tamiko Takeuchi;H. Tobita;H. Ogino
The first manganese derivative of the donor-stabilized bis(silylene) complex (OC) 4 Mn{SiMe 2 ...O(Me)... SiMe 2 } has been synthesized by the photolysis of (OC) 5 MnSiMe 2 SiMe 2 SiMe 2 OMe. The X-ray structure analysis of this complex revealed its distorted-octahedral structure with two short Mn-Si bonds and a planar MnSi 2 O chelate ring