Surface Base Sites of MgO Covered with Al2O3: XANES Analysis of Al and Mg K-edges
Surface Base Sites of MgO Covered with Al2O3: XANES Analysis of Al and Mg K-edges
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DOI：
10.1007/s11244-010-9502-z
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发表时间：
2010-04
影响因子：
3.6
通讯作者：
H. Matsuhashi;Koji Nagashima;Nobuaki Naijo;H. Aritani
中科院分区：
文献类型：
--
作者：
H. Matsuhashi;Koji Nagashima;Nobuaki Naijo;H. Aritani
通过在乙酸乙酯中在Mg（OH）2上分解Al（OCH（CH3）2）3来制备包含用Al2O3覆盖的MgO的固体碱。含Al量大于10 mol%的催化剂不溶于丙酮。铝主要占据八面体网站在低含量范围内，四面体结构是在高范围内的主要之一。
Solid bases comprising MgO covered with Al2O3were prepared by decomposition of Al(OCH(CH3)2)3over Mg(OH)2in ethyl acetate. Catalysts containing more than 10 mol% Al were insoluble in acetone. Aluminum occupied mainly octahedral sites in the low content range; tetrahedral structure being the principal one in the high range.