Evaluated Kinetic and Photochemical Data for Atmospheric Chemistry: Supplement II. CODATA Task Group on Gas Phase Chemical Kinetics
Evaluated Kinetic and Photochemical Data for Atmospheric Chemistry: Supplement II. CODATA Task Group on Gas Phase Chemical Kinetics
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DOI：
10.1063/1.555721
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发表时间：
1984-10
影响因子：
4.3
通讯作者：
D. L. Baulch;R. A. Cox;R. F. Hampson;J. Kerr;J. Troe;R. T. Watson
中科院分区：
文献类型：
--
作者：
D. L. Baulch;R. A. Cox;R. F. Hampson;J. Kerr;J. Troe;R. T. Watson
本文更新和扩展了以前对大气化学中中性物质气相化学反应动力学和光化学的临界评价[J. Phys. Chem. Ref. Data 9，295（1980）; 11 327（1982）]。这项工作已经进行了由作者的CODATA任务组的气相化学动力学的主持下。已经为256个热反应和光化学反应编写了数据表，其中载有现有实验数据的摘要，并附有实验程序的详细说明。对于每个反应，在298 K下的速率系数的优选值与温度依赖性一起给出。讨论了优选值的选择;并对每个反应的速率系数和温度系数的准确度进行了估计。数据表旨在提供所需的基本物理化学数据，作为模拟大气化学的计算的输入。一个表格总结了pr...
This paper updates and extends previous critical evaluations of the kinetics and photochemistry of gas phase chemical reactions of neutral species involved in atmosphere chemistry [J. Phys. Chem. Ref. Data 9, 295 (1980); 11 327 (1982)]. The work has been carried out by the authors under the auspices of the CODATA Task Group on Gas Phase Chemical Kinetics. Data sheets have been prepared for 256 thermal and photochemical reactions, containing summaries of the available experimental data with notes giving details of the experimental procedures. For each reaction, a preferred value of the rate coefficient at 298 K is given together with a temperature dependence where possible. The selection of the preferred value is discussed; and estimates of the accuracies of the rate coefficients and temperature coefficients have been made for each reaction. The data sheets are intended to provide the basic physical chemical data needed as input for calculations which model atmospheric chemistry. A table summarizing the pr...