Local protonation control using plasmonic activation

Local protonation control using plasmonic activation
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DOI:
10.1039/c4cc04642k
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发表时间:
2014-01-01
影响因子:
4.9
通讯作者:
Deckert, Volker
Deckert, Volker
中科院分区:
化学2区
文献类型:
--
作者:
Singh, Pushkar;Deckert, Volker

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利用表面增强拉曼散射(Sers)和针尖增强拉曼散射(TERS),在室温下研究了4-巯基吡啶(4-MPY)在银纳米粒子存在下的光活化质子化过程。该反应可以通过激发波长和大气条件来控制,因此,提供了一种用于质子化的位点特异性控制的工具。
Localized protonation of 4-mercaptopyridine (4-MPY), activated by light in the presence of silver nanoparticles is monitored under ambient conditions using surface-enhanced Raman scattering (SERS) and tip-enhanced Raman scattering (TERS). The reaction can be controlled by the excitation wavelength and the atmospheric conditions, thus, providing a tool for site-specific control of protonation.