Synthesis and chemistry of enantiomerically pure 10,11-dihydrodibenzo[b,f]thiepines.
Synthesis and chemistry of enantiomerically pure 10,11-dihydrodibenzo[b,f]thiepines.
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对映体纯的10,11-二氢二苯并[b,f]噻吩的合成和化学。
DOI：
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发表时间：
2006
影响因子：
3.2
通讯作者：
H. Phetmung
中科院分区：
文献类型：
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作者：
P. Wyatt;A. Hudson;J. Charmant;A. Orpen;H. Phetmung
使用硫二咪唑与各种双锂化碳片段组合有效地构建了几种手性硫杂环庚三烯。发现这些硫杂环庚三烯中的硫原子与二苯硫醚相比不具有反应性。
Several chiral thiepines were efficiently constructed using sulfur diimidazole in combination with a variety of bislithiated carbon fragments. The sulfur atom in these thiepines is found to be unusually unreactive compared to diphenylsulfide.