High gas storage capacities and stepwise adsorption in a UiO type metal-organic framework incorporating Lewis basic bipyridyl sites
High gas storage capacities and stepwise adsorption in a UiO type metal-organic framework incorporating Lewis basic bipyridyl sites
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包含路易斯碱性联吡啶位点的 UiO 型金属有机骨架中的高储气容量和逐步吸附
DOI：
10.1039/c3cc48275h
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发表时间：
2014-01-01
影响因子：
4.9
通讯作者：
Zhao, Xuebo
中科院分区：
文献类型：
--
作者：
Li, Liangjun;Tang, Sifu;Zhao, Xuebo
合成了一种具有刘易斯碱性联吡啶中心的UiO型MOF，并对其结构进行了表征。经索氏抽提活化后，该MOF对H2-、CH 4和CO2具有较高的储存容量，对液态CO2和溶剂具有不寻常的分步吸附，表明其在不同吸附位点上具有顺序填充机制.
A UiO type MOF with Lewis basic bipyridyl sites was synthesized and structurally characterized. After being activated by Soxhlet-extraction, this MOF exhibits high storage capacities for H-2, CH4 and CO2, and shows unusual stepwise adsorption for liquid CO2 and solvents, indicating a sequential filling mechanism on different adsorption sites.