Thermoelectric power enhancement of PEDOT:PSS in high-humidity conditions

Thermoelectric power enhancement of PEDOT:PSS in high-humidity conditions
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DOI:
10.7567/apex.7.031601
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发表时间:
2014-03-01
影响因子:
2.3
通讯作者:
Ishida, Takao
Ishida, Takao
中科院分区:
物理与天体物理3区
文献类型:
--
作者:
Wei, Qingshuo;Mukaida, Masakazu;Ishida, Takao

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我们报告了在高湿度条件下聚(3,4-乙撑二氧噻吩):聚(苯乙烯磺酸盐)(PEDOT:PSS)的热电功率因数从23 +/- 5增加到225 +/- 130 μ W/(m.K-2)。这种增强主要是由于表观塞贝克系数的增加,这可能与PEDOT在空气中吸水或电化学反应后的形态变化有关。我们的研究结果表明,在PEDOT:PSS系统中的水的积极影响,并表明需要良好控制的测量条件,特别是湿度,在评估导电有机材料的性能。(C)2014日本应用物理学会
We report an increase in the thermoelectric power factor of poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) from 23 +/- 5 to 225 +/- 130 mu W/(m.K-2) in high-humidity conditions. This enhancement was caused mainly by an increase in the apparent Seebeck coefficient, which could be related to morphological change after water absorption or electrochemical reaction of PEDOT in air. Our results demonstrate a positive effect of water in the PEDOT:PSS system and indicate the need for well-controlled measurement conditions, particularly humidity, in evaluating the performance of conducting organic materials. (C) 2014 The Japan Society of Applied Physics