The development of organic super electron donors.
The development of organic super electron donors.
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有机超电子给体的开发。
DOI：
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发表时间：
2012
期刊：
影响因子：
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通讯作者：
John A. Murphy
中科院分区：
文献类型：
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作者：
Sheng;Hardeep Farwaha;John A. Murphy
在过去的十年中，已经设计和制备了一系列非常强的有机电子给体;它们的氧化还原电位比任何以前的中性有机给体更负，并且超过E（1/2）= -1 V vs.饱和甘汞电极（SCE）。他们的能力，以减少广泛的有机官能团已被证明，本文提供了一个概述的主要进展，在该地区和指导原则，这些试剂的设计。
In the past decade, a host of exceptionally strong organic electron donors has been designed and prepared; their redox potentials are more negative than any previous neutral organic donors and extend beyond E(1/2) = -1 V vs. the saturated calomel electrode (SCE). Their ability to reduce a wide range of organic functional groups has been demonstrated and this article provides an overview of the main advances in the area and the guiding principles for the design of these reagents.