Photophysical Properties and Redox Potentials of Photosensitizers for Organic Photoredox Transformations
Photophysical Properties and Redox Potentials of Photosensitizers for Organic Photoredox Transformations
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DOI：
10.1055/a-1390-9065
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发表时间：
2021-02
期刊：
影响因子：
2
通讯作者：
Thomas S. Teets;Yanyu Wu;Dooyoung Kim
中科院分区：
文献类型：
--
作者：
Thomas S. Teets;Yanyu Wu;Dooyoung Kim
摘要光氧化还原催化已被证明是合成有机化学中一种强有力的工具。合理设计具有良好光催化性能的光敏剂是光氧化还原有机转化的重要进展。本文综述了分子光敏剂的基本基态和激发态光物理和电化学性质，这些性质是决定分子光敏剂光催化活性的重要因素。
Abstract Photoredox catalysis has proven to be a powerful tool in synthetic organic chemistry. The rational design of photosensitizers with improved photocatalytic performance constitutes a major advancement in photoredox organic transformations. This review summarizes the fundamental ground-state and excited-state photophysical and electrochemical attributes of molecular photosensitizers, which are important determinants of their photocatalytic reactivity.