Synthesis and self-photooxygenation of alkenyl-linked [60]fullerene derivatives. A regioselective ene reaction.
Synthesis and self-photooxygenation of alkenyl-linked [60]fullerene derivatives. A regioselective ene reaction.
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烯基连接的[60]富勒烯衍生物的合成和自光氧化。
DOI：
10.1021/ol025690l
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发表时间：
2002
期刊：
影响因子：
5.2
通讯作者：
M. Orfanopoulos
中科院分区：
文献类型：
--
作者：
N. Chronakis;G. Vougioukalakis;M. Orfanopoulos
[反应：链烯基连接的C（60）衍生物通过优先夺取双键富勒烯侧的烯丙基氢而区域选择性地进行自光氧化。
[reaction: see text] Alkenyl-linked C(60) derivatives undergo self-photooxygenation regioselectively, by the preferential abstraction of allylic hydrogens on the fullerene side of the double bond.