Sn-6 and Na-4 Oxo Clusters Based Non-centrosymmetric Framework for Solution Iodine Absorption and Second Harmonic Generation Response
Sn-6 and Na-4 Oxo Clusters Based Non-centrosymmetric Framework for Solution Iodine Absorption and Second Harmonic Generation Response
复制标题
基于 Sn-6 和 Na-4 羰基团簇的溶液碘吸收和二次谐波产生响应的非中心对称框架
DOI：
10.1021/acs.inorgchem.0c03448
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发表时间：
2021
影响因子：
4.6
通讯作者：
Zhang Lei
中科院分区：
文献类型：
--
作者：
Zhu Yu;Li Dong-Sheng;Zhang Jian;Zhang Lei
以{Sn6}和{Na4}团簇单元为基础，通过草酸配体成功构建了三维非中心对称团簇有机骨架，属于锡氧团簇领域首个含有不同团簇单元的三维骨架。除了有趣的结构特征外，所获得的3D框架不仅可以有效吸附碘分子，而且在1064 nm Q开关激光下显示出二次谐波产生响应。
A three-dimensional non-centrosymmetric cluster organic framework has successfully been built from the {Sn6} and {Na4} cluster units via the oxalate ligand, which belongs to the first 3D framework containing different cluster units in the field of tin-oxo clusters. Besides the interesting structural characteristics, the obtained 3D framework not only can efficiently adsorb the iodine molecules but also displays the second harmonic generation response under the 1064 nm Q-switch laser.