Selective N2O Removal from the Process Gas of Nitric Acid Plants Over Ceramic 12CaO · 7Al2O3 Catalyst
Selective N2O Removal from the Process Gas of Nitric Acid Plants Over Ceramic 12CaO · 7Al2O3 Catalyst
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陶瓷12CaO·7Al2O3催化剂选择性脱除硝酸装置工艺气体中的N2O
DOI：
10.1007/s10562-008-9619-x
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发表时间：
2008
影响因子：
2.8
通讯作者：
Z. Sojka
中科院分区：
文献类型：
--
作者：
M. Ruszak;M. Inger;S. Witkowski;M. Wilk;A. Kotarba;Z. Sojka
Catalytic high temperature decomposition (secondary abatement) of nitrous oxide over calcium aluminate 12CaO · 7Al2O3 (mayenite) was studied in the model laboratory tests (TPSR) and pilot units (steady-state) using the real feed. X-ray diffraction (XRD), scanning electron microscopy (SEM), N2-sorption (BET), electron paramagnetic resonance (EPR) and Raman spectroscopies were used to characterize the synthesized material. The catalyst exhibited high efficiency and selectivity in N2O removal, reaching practically 100% conversion at 1150 K without appreciable total losses of NOx. Owing to its high thermal stability and resistivity to sintering and low cost of production raw materials, mayenite was found to be a promising catalyst for economically appealing secondary abatement of nitrous oxide in nitric acid plants.
影响因子：
8.6
作者：
Olga Trofymluk;Y. Toda;And Hideo Hosono;A. Navrotsky
通讯作者：
Olga Trofymluk;Y. Toda;And Hideo Hosono;A. Navrotsky