A concise access to (polyfluoroaryl)allenes by Cu-catalyzed direct coupling with propargyl phosphates.
A concise access to (polyfluoroaryl)allenes by Cu-catalyzed direct coupling with propargyl phosphates.
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DOI：
10.1021/ol300886k
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发表时间：
2012-05
期刊：
影响因子：
5.2
通讯作者：
Akihiro Nakatani;K. Hirano;T. Satoh;M. Miura
中科院分区：
文献类型：
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作者：
Akihiro Nakatani;K. Hirano;T. Satoh;M. Miura
开发了一种多氟芳烃与丙烯基磷酸酯直接偶联的铜基催化剂体系。该催化剂可以快速、简捷地获得(多氟芳基)烯类化合物，可作为合成含氟功能材料的重要构件。
A copper-based catalyst system for the direct coupling of polyfluoroarenes with propargyl phosphates has been developed. The catalysis can provide a rapid and concise access to (polyfluoroaryl)allenes, which can be important building blocks for the synthesis of fluorinated functional materials.