Induction of gamma-turn-like structure in ferrocene bearing dipeptide chains via conformational control.
Induction of gamma-turn-like structure in ferrocene bearing dipeptide chains via conformational control.
复制标题
通过构象控制在二茂铁二肽链中诱导类γ转角结构。
DOI：
10.1021/ol052510
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发表时间：
2006
期刊：
影响因子：
5.2
通讯作者：
T. Hirao
中科院分区：
文献类型：
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作者：
T. Moriuchi;Takayoshi Nagai;T. Hirao
[结构：作为中心反向转角单元的二茂铁支架与二肽链（-L-Pro-L-Ala-NHPy）的组合被证明诱导反向γ转角样和反平行β折叠样结构。在含有异手性二肽链（-L-Pro-D-Ala-NHPy）的二茂铁中，只有反平行的β-折叠结构，通过分子间氢键网络实现了高度有序的自组装。
[structure: see text] A combination of the ferrocene scaffold as a central reverse-turn unit with the dipeptide chains (-L-Pro-L-Ala-NHPy) was demonstrated to induce both inverse gamma-turn-like and antiparallel beta-sheet-like structures. Only the antiparallel beta-sheet-like structure was formed in the ferrocene bearing the heterochiral dipeptide chains (-L-Pro-D-Ala-NHPy), in which highly organized self-assembly was achieved through a network of intermolecular hydrogen bonds.
DOI：
--
发表时间：
2007
期刊：
影响因子：
--
作者：
H. Ishida;Y. Maekawa;F. Horii;T. Yamamoto;T.Yamamoto;K.Nozaki;H.Ishida;浦上 直人;T. Yamamoto;T. Yamamoto;浅野 隆聡;今田 絢子;浅野 隆聡;山本 隆;山本 隆;山本 隆;T. Yamamoto;J. Imada
通讯作者：
J. Imada