C-H bond functionalization based on metal carbene migratory insertion
C-H bond functionalization based on metal carbene migratory insertion
复制标题
基于金属卡宾迁移插入的C-H键功能化
DOI：
10.1039/c5cc00497g
复制
发表时间：
2015-01-01
影响因子：
4.9
通讯作者：
Wang, Jianbo
中科院分区：
文献类型：
--
作者：
Hu, Fangdong;Xia, Ying;Wang, Jianbo
金属卡宾迁移插入交叉偶联反应是一种以重氮化合物为反应伙伴的新型偶联反应。自2011年以来，卡宾迁移插入过程被成功地合并到C-H键活化中，这是一个有趣的发展。按照这一思路，在过去的几年里记录了一系列的调查。这篇专题文章概述了这方面的发展。
Cross-coupling reactions involving metal carbene migratory insertion have been established as a new type of coupling reaction with diazo compounds as the reaction partners. Since 2011, an interesting development has been made in which the carbene migratory insertion process is successfully merged into C-H bond activations. Along this line, a series of investigations have been documented in the past few years. This feature article summarizes the developments in this area.