Metal-organic framework-based heterogeneous catalysts for the conversion of C1 chemistry: CO, CO2 and CH4
Metal-organic framework-based heterogeneous catalysts for the conversion of C1 chemistry: CO, CO2 and CH4
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用于 C1 化学转化的金属有机骨架多相催化剂：CO、CO2 和 CH4
DOI：
10.1016/j.ccr.2019.02.001
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发表时间：
2019-05
影响因子：
20.6
通讯作者：
Bu Xian-He
中科院分区：
文献类型：
--
作者：
Cui Wen-Gang;Zhang Guo-Ying;Hu Tong-Liang;Bu Xian-He
碳1化学的催化作用，特别是对一氧化碳(CO)、二氧化碳(CO2)和甲烷(CH4)的催化作用，对于清洁生产燃料和化学品以及未来的能源可持续性至关重要。然而，由于这些C1分子的相对惰性和低反应性，它们的活化和转化为清洁燃料和高附加值化学品仍然是艰巨的挑战。在这种背景下，金属有机骨架(MOF)作为相对较新的晶态多孔材料，在设计和合成各种功能纳米材料以应对这些挑战方面具有很好的前景。本文系统地综述了近年来MOF基多相催化剂在CO、CO2和CH4转化为高附加值化学品方面的研究进展。重点介绍了该催化剂的催化活性、反应机理和催化剂设计。此外，还讨论了MOF催化剂在C1化学转化中的主要挑战和机遇，以概述这一正在进行的研究领域的进一步发展。预计这一综述将为化学家和材料学家提供有用的指导，帮助他们设计更好的基于MOF的催化剂，用于C1化合物的化学转化。
Catalysis of C1 chemistry, especially for carbon monoxide (CO), carbon dioxide (CO2) and methane (CH4), is critically important for the clean production of fuels and chemicals and future energy sustainability. However, due to the relatively inert nature and low reactivity of these C1 molecules, their activation and transformation into clean fuels and high value-added chemicals still remain formidable challenges. In this context, metal-organic frameworks (MOFs), as relatively new emerging crystalline porous materials, have been shown to be promising heterogeneous catalysts or supports/precursors in the design and synthesis of various functional nanomaterials for addressing these challenges. In this review, the recent advances in MOF-based heterogeneous catalysts for transforming CO, CO2and CH4into high value-added chemicals are systematically reviewed. Emphasis is mainly placed on the catalytic reactivity, reaction mechanism and catalyst design. Additionally, major challenges and opportunities for MOF catalysts in the conversion of C1 chemistry are discussed to outline aspects for further development in this ongoing research field. It is anticipated that this review will provide a useful guide to chemists and material scientists attempting to design better MOF-based catalysts for the chemical conversion of C1 compounds.
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