Preparation of macrocyclic tertiary amine complexes of nickel(II) by alkylation of coordinated amine. Crystal structure of a monoazide bridged dimer of (N-tetramethylcyclam)nickel(II)
Preparation of macrocyclic tertiary amine complexes of nickel(II) by alkylation of coordinated amine. Crystal structure of a monoazide bridged dimer of (N-tetramethylcyclam)nickel(II)
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通过配位胺烷基化制备镍(II)大环叔胺配合物。
DOI：
10.1021/ja00815a057
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发表时间：
1974
影响因子：
15
通讯作者：
E. Barefield
中科院分区：
文献类型：
--
作者：
F. Wagner;M. Mocella;M. D'aniello;A. Wang;E. Barefield
最近，我们报道了1，2，4，6，6，6，6，6，6，6，5，5，6-三甲基-4-甲基-4-羟基-4-羟基-4-羟基-4-羟基-4-酮及其金属配合物的制备。这些络合物的一个令人惊讶和令人失望的性质是它们的不稳定性，这显然是由动力学过程所决定的一组氮施主构型的结果
Recently we reported the preparations of 1 and some of its metal complexes. 1 Asurprising and disappointing property of these complexes was their lability, which was apparently a result of the set of nitrogen donor con-figurations that was dictated by the kinetic precesses