Organic Stereochemistry: Experimental and Computational Methods

Organic Stereochemistry: Experimental and Computational Methods
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DOI:
10.1002/9783527688166
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发表时间:
2015-08
期刊:
--
影响因子:
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通讯作者:
Hua-Jie Zhu
Hua-Jie Zhu
中科院分区:
其他
文献类型:
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作者:
Hua-Jie Zhu

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正文被清楚地分成三个部分关于基本原理,光谱学和计算技术,和在有机合成中的应用。第一部分简要介绍了手性和立体化学领域,而第二部分涵盖了不同的方法,例如旋光、电子圆二色性、振动圆二色性和拉曼光谱。第三部分接着描述有机合成中的选择性实例,按反应类型分类,即对映选择性、化学选择性和立体选择性反应。最后一章是关于天然产物的全合成,这是本书的最后一章。
The text is clearly divided into three sections on fundamentals, spectroscopic and computational techniques, and applications in organic synthesis. The first part provides a brief introduction to the field of chirality and stereochemistry, while the second part covers the different methodologies, such as optical rotation, electronic circular dichroism, vibrational circular dicroism, and Raman spectroscopy. The third section then goes on to describe selective examples in organic synthesis, classified by reaction type, i.e. enantioselective, chemoselective and stereoselective reactions. A final chapter on total synthesis of natural products rounds off the book.