Highly regioselective and stereoselective allylation of aldehydes via palladium-catalyzed in situ hydrostannylation of allenes
Highly regioselective and stereoselective allylation of aldehydes via palladium-catalyzed in situ hydrostannylation of allenes
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DOI：
10.1021/ol0064563
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发表时间：
2000-11-02
期刊：
影响因子：
5.2
通讯作者：
Cheng, CH
中科院分区：
文献类型：
--
作者：
Chang, HM;Cheng, CH
[GRAPHICS]Highly regio and stereoselective allylation of aldehydes by allenes proceeds smoothly in aqueous/organic media in the presence of PdCl2-(PPh3)(2), HCl, and SnCl2. The reaction likely occurs via hydrostannylation of allenes and allylation of aldehydes by the in situ generated allyltrichlorotins to afford the final products.
