(2,2'-Bipyridine-κ(2)N,N'){N-[(2-oxidonaphthalen-1-yl-κO)methyl-idene]-l-valinato-κO}copper(II) trihydrate.

(2,2'-Bipyridine-κ(2)N,N'){N-[(2-oxidonaphthalen-1-yl-κO)methyl-idene]-l-valinato-κO}copper(II) trihydrate.
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(2,2-联吡啶-γ(2)N,N){N-[(2-氧化萘-1-基-γO)亚甲基]-l-缬氨酸-γO}三水合铜(II)。

DOI:
10.1107/s1600536812022702
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发表时间:
2012
期刊:
Acta crystallographica. Section E, Structure reports online
影响因子:
--
通讯作者:
Zhang,Pengfei
Zhang,Pengfei
中科院分区:
--
文献类型:
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作者:
Zuo,Jian;Bi,Caifeng;Fan,Yuhua;Zhang,Nan;Zhang,Pengfei

文献摘要

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在配合物[Cu(C16 H15 NO3)(C10 H8 N2)]·3 H2O中,Cu Ⅱ原子分别与Schiff碱配体的O,N,O′-给体原子和2,2 ′-联吡啶配体的两个N原子以五配位,形成畸变的四方锥构型.在晶体中,分子通过O-H O氢键连接成平行于(011)的二维网络。
In the title complex, [Cu(C16H15NO3)(C10H8N2)]·3H2O, the CuII atom is five coordinated by O,N,O′-donor atoms of the Schiff base ligand and by two N atoms of the 2,2′-bipyridine ligand in a distorted square-pyramidal geometry. In the crystal, molecules are linked into a two-dimensional network parallel to (011) by O—H⋯O hydrogen bonds.