A novel diaminoborate ligand system derived from 1,8-diaminonaphthalene and 9-BBN: Preparation of titanium and zirconium complexes and crystal structure of the titanium complex
A novel diaminoborate ligand system derived from 1,8-diaminonaphthalene and 9-BBN: Preparation of titanium and zirconium complexes and crystal structure of the titanium complex
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DOI：
10.1039/a607194e
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发表时间：
1997-01-21
影响因子：
4.9
通讯作者：
Kol, M
中科院分区：
文献类型：
--
作者：
BarHaim, G;Shach, R;Kol, M
1，8-二氨基萘与1当量的N，N-二氨基萘发生选择性反应。9-BBN形成桥联胺-氨基硼烷，并与2当量。9-BBN形成非桥联的双(氨基硼烷)；这些氨基硼烷通过与钛和锆二甲酰胺反应得到一种新的二氨基硼酸盐(4E，1-)配体体系。
1,8-Diaminonaphthalene reacts selectively with 1 equiv. of 9-BBN to form a bridging amine-aminoborane, and with 2 equiv. of 9-BBN to form a non-bridging bis(aminoborane); these aminoboranes give rise to a novel diaminoborate (4e,1-) ligand system by reactions with dimethylamides of titanium and zirconium.