Ni-Catalyzed Carboxylation of Unactivated Alkyl Chlorides with CO2
Ni-Catalyzed Carboxylation of Unactivated Alkyl Chlorides with CO2
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DOI：
10.1021/jacs.6604088
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发表时间：
2016-06-22
影响因子：
15
通讯作者：
Martin, Ruben
中科院分区：
文献类型：
--
作者：
Borjesson, Marino;Moragas, Toni;Martin, Ruben
本文叙述了未活化的伯、仲、叔烷基氯与CO在常压下的催化羧化反应。该协议代表了未活化的烷基氯的第一个分子间交叉亲电偶联，从而导致交叉偶联竞技场的新知识。
A catalytic carboxylation of unactivated primary, secondary, and tertiary alkyl chlorides with CO, at atmospheric pressure is described. This protocol represents the first intermolecular cross-electrophile coupling of unactivated alkyl chlorides, thus leading to new knowledge in the cross-coupling arena.