The homogeneous nucleation of nonane
The homogeneous nucleation of nonane
复制标题
壬烷的均相成核
DOI：
10.1063/1.447496
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发表时间：
1984
影响因子：
4.4
通讯作者：
R. A. Zalabsky
中科院分区：
文献类型：
--
作者：
G. W. Adams;J. Schmitt;R. A. Zalabsky
正壬烷的均匀成核率已在精密快速膨胀室中测量为温度和过饱和度的函数。在 215-270 K 的温度范围内，测量的成核率范围为 102 至 105 滴/cm3。结果已与经典理论以及具有 RKC 替换因子的经典理论进行了比较。 RKC 理论函数形式是拟合数据的经验速率方程的基础。给出了用于减少数据的热力学常数的完整列表。
The homogeneous nucleation rate of n‐nonane has been measured as a function of temperature and supersaturation ratio in a precision fast‐expansion chamber. The measured nucleation rate ranges from 102 to 105 drops/cm3 over the temperature range 215–270 K. The results have been compared to the classical theory and to the classical theory with the RKC replacement factor. The RKC theory functional form is the basis for an empirical rate equation to fit the data. A full listing of the thermodynamic constants used for the reduction of the data is given.