Approaches to rotary molecular motors
Approaches to rotary molecular motors
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DOI：
10.1351/pac200678071299
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发表时间：
2006-07-01
影响因子：
1.8
通讯作者：
Knobler, Carolyn B.
中科院分区：
文献类型：
--
作者：
Hawthorne, M. Frederick;Ramachandran, Bhaskar M.;Knobler, Carolyn B.
最近的兴趣已经加强了在寻找分子马达和执行器能够提供有用的工作，电化学或光化学电源的控制下的纳米器件。虽然这些人造分子机器中的许多被设计成提供直线运动，但很少有人提出在分子内重排的时间尺度特征上控制旋转运动的传递。目前正在研究commo-bis-dicarbollide metallcarborane结构对这种旋转分子马达的可能设计和合成的适应性。将报告实现这一目标的进展情况。
Interest has recently intensified in the search for molecular motors and actuators capable of delivering useful work to nanodevices under the control of electrochemical or photochemical power sources. While many of these man-made molecular machines are designed to deliver rectilinear motion, very few are proposed for the controlled delivery of rotary motion on the time scale characteristic of intramolecular rearrangements. The adaptation of commo-bis-dicarbollide metallacarborane structures to the possible design and synthesis of such rotary molecular motors is now under investigation. Progress toward this goal will be reported.