Triangular Triplatinum(0) Complex with Bridging Germylene Ligands. Insertion of Alkyne into the Pt‒Ge Bond Rather Than the Pt‒Pt Bond
Triangular Triplatinum(0) Complex with Bridging Germylene Ligands. Insertion of Alkyne into the Pt‒Ge Bond Rather Than the Pt‒Pt Bond
复制标题
将炔烃插入 Pt-Ge 键而非 Pt-Pt 键中的三角形三铂 (0) 配合物。
DOI：
10.1039/c4cc00727a
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发表时间：
2014
影响因子：
4.9
通讯作者：
Kohtaro Osakada
中科院分区：
文献类型：
--
作者：
Makoto Tanabe;Kimiya Tanaka;Shumpei Omine;Kohtaro Osakada
一种新的三角三铂(0)配合物，具有桥联二苯基亚甲锗烷基配体[{Pt(PMe3)}3(μ-GePh2)3]，将ZCCZ (Z = COOMe)插入到Pt-Ge键中。该产物在Pt3平面上含有μ3-η2(∥)-CZCZ-GePh2配体。两个 HCCZ 分子反应生成具有螯合 C、Ge 和 Ge、Ge 配体的 Pt3 络合物。
A new triangular triplatinum(0) complex with bridging diphenylgermylene ligands, [{Pt(PMe3)}3(μ-GePh2)3], undergoes insertion of ZCCZ (Z = COOMe) into a Pt–Ge bond. The product contains a μ3-η2(∥)-CZCZ-GePh2 ligand on the Pt3 plane. Two molecules of HCCZ react to afford the Pt3 complex with chelating C, Ge- and Ge, Ge-ligands.