Stronger host-guest binding does not necessarily give brighter particles: a case study on polymeric AIEE-tunable and size-tunable supraspheres

Stronger host-guest binding does not necessarily give brighter particles: a case study on polymeric AIEE-tunable and size-tunable supraspheres
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更强的主客体结合不一定会产生更亮的粒子:聚合物 AIEE 可调和尺寸可调超球体的案例研究

DOI:
10.1039/c8cc04905j
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发表时间:
2018
影响因子:
4.9
通讯作者:
Cao Derong
Cao Derong
中科院分区:
化学2区
文献类型:
--
作者:
Xu Linxian;Wang Rongrong;Cui Wei;Wang Lingyun;Meier Herbert;Tang Hao;Cao Derong

文献摘要

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超球由柱[5]芳烃基线性聚合物(主体)和几种多主题客体制备。根据在纳米系统中的主-客体结合研究,纳米颗粒的光学和结构性质(荧光能力、密度和粒径)与主-客体结合亲和力无关,而是与相对荧光量子产率相关。
Supraspheres were prepared from a pillar[5]arene-based linear polymer (the host) and several multitopic guests. According to host–guest binding studies in nanosystems, the optical and structural properties (fluorescence capability, density, and particle size) of the nanoparticles were correlated not with the host–guest binding affinities, but with the relative fluorescence quantum yield.