Mild and efficient method for the cleavage of benzylidene acetals using HClO4-SiO2 and direct conversion of acetals to acetates

Mild and efficient method for the cleavage of benzylidene acetals using HClO4-SiO2 and direct conversion of acetals to acetates
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DOI:
10.1016/j.tetlet.2006.03.133
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发表时间:
2006-05-29
影响因子:
1.8
通讯作者:
Misra, Anup Kumar
Misra, Anup Kumar
中科院分区:
化学4区
文献类型:
--
作者:
Agnihotri, Geetanjali;Misra, Anup Kumar

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HClO_4-SiO_2催化剂已成功地用于苄叉缩醛的脱保护和苄叉缩醛直接转化为相应的二-O-乙酸酯。反应非常快,产率优异。(c)2006爱思唯尔有限公司保留所有权利。
HClO4-SiO2 has been used successfully for the deprotection of benzylidene acetals and the direct conversion of benzylidene acetals to the corresponding di-O-acetates. The reactions are very fast and yields are excellent. (c) 2006 Elsevier Ltd. All rights reserved.