A New Synthesis of Functional Dyes from 2-Acenaphtho[1,2-c]pyrrole
A New Synthesis of Functional Dyes from 2-Acenaphtho[1,2-c]pyrrole
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DOI：
10.3987/com-03-s58
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发表时间：
2003-12
期刊：
影响因子：
0.6
通讯作者：
N. Ono;Takanori Yamamoto;Naomi Shimada;Kenji Kuroki;M. Wada;Ryouhei Utsunomiya;T. Yano;H. Uno;T. Murashima
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文献类型：
--
作者：
N. Ono;Takanori Yamamoto;Naomi Shimada;Kenji Kuroki;M. Wada;Ryouhei Utsunomiya;T. Yano;H. Uno;T. Murashima
将苊并[1，2-c]吡咯单元引入到π共轭体系中可以有效地得到窄HOMO-LUMO带隙的材料，并且与苊环稠合的π共轭聚合物、卟啉和硼二吡咯亚甲基染料的吸收光谱都发生了大幅度的红移。
Incorporation of acenaphtho[1,2-c]pyrrole units into the π-conjugated systems is very effective to get the narrow HOMO-LUMO gap materials, and the absorption spectra of π-conjugated polymers, porphyrins, and boron dipyrromethene dyes fused with acenaphthene rings are extensively red-shifted.