A periodic reaction in homogeneous solution and its relation to catalysis.

A periodic reaction in homogeneous solution and its relation to catalysis.
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DOI:
10.1021/ja01439a007
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发表时间:
1921-06-01
影响因子:
15
通讯作者:
Bray, WC
Bray, WC
中科院分区:
化学1区
文献类型:
--
作者:
Bray, WC

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1916年,AL Caulkins和作者开始研究过氧化氢作为氧化剂和还原剂的双重作用。所考虑的反应是碘氧化成碘酸,以及碘酸还原成碘,即:
In 1916 AL Caulkins and the writer began an investigation of the dual róle of hydrogen peroxide as an oxidizing agent and as a reducing agent. The reactions considered were the oxidation of iodine to iodic acid, and the reduction of iodic acid to iodine, viz.: