Synthesis of multiarmed thienylene-tetrafluorophenylene alternating copolymers under transition-metal-free conditions
Synthesis of multiarmed thienylene-tetrafluorophenylene alternating copolymers under transition-metal-free conditions
复制标题
无过渡金属条件下多臂噻吩基-四氟亚苯基交替共聚物的合成
DOI：
10.1021/acs.macromol.6b01660
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发表时间：
2016
期刊：
影响因子：
5.5
通讯作者：
Takanobu Sanji; Junko Kakinuma; Tomokazu Iyoda
中科院分区：
文献类型：
--
作者：
Saitoh;M.;Isozaki;Y.;Yao;J.X.;Ji;Z.S.;Takanobu Sanji; Junko Kakinuma; Tomokazu Iyoda
在无过渡金属存在的条件下，通过2-五氟苯基-5-三甲基硅基噻吩的聚合反应，可控合成了多臂交替噻吩基-四氟亚苯基共聚物。通过1，4-和1，3-双[（三甲基硅基）乙炔基]苯和1，3，5-三[（三甲基硅基）乙炔基]苯与四丁基氟化铵反应制备了所设计的二官能和三官能氟硅酸盐引发剂，得到了具有可控分子量和相对低分散性的双臂（I形和V形）和三臂（Y形）聚合物。使用NMR光谱成功地确认了聚合物的结构。
The controlled synthesis of multiarmed alternating thienylene–tetrafluorophenylene copolymers by the polymerization of 2-pentafluorophenyl-5-trimethylsilylthiophene under transition-metal-free conditions is demonstrated. The designed di- and trifunctional fluorosilicate initiators prepared by the reaction of 1,4- and 1,3-bis[(trimethylsilyl)ethynyl]benzene and 1,3,5-tris[(trimethylsilyl)ethynyl]benzene and tetrabutylammonium fluoride afford two-arm (I- and V-shaped) and three-arm (Y-shaped) polymers with controlled molecular weights and relatively low dispersities. The structures of the polymers were successfully confirmed using NMR spectroscopy.