Living and controlled polymerization : synthesis, characterization and properties of the respective polymers and copolymers
Living and controlled polymerization : synthesis, characterization and properties of the respective polymers and copolymers
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发表时间：
2005
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通讯作者：
J. Jagur-grodzinski
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作者：
J. Jagur-grodzinski
活性/可控聚合技术为聚合物化学开辟了新的前景。这一领域的主要权威及其先驱为这本集体卷贡献了章节。可控聚合技术使得制备具有预定分子量和窄多分散性的聚合物、共聚物和嵌段共聚物成为可能，其中的官能团或生物活性分子可以被放置在明确的位置。它们还使制备具有精确确定的结构和改进的性能的先进聚合物结构成为可能。此外，它们还提供了从单体制备新型聚合物材料的机会，这些单体以前不适合或不适合用于此类目的。其中一些聚合物材料的性质可能与现有材料的性质有很大不同。它们为新的应用提供了机会。几项专利已被批准用于药物输送、生物相容性表面、热塑性弹性体、湿气固化密封剂等特殊应用。在纳米技术、医疗设备、智能聚合物、传感器、智能分离技术、光纤和其他光学应用、各种生物材料等专业领域，肯定会出现更多基于生物/可控聚合技术制造的聚合物的产品。
The living/controlled polymerisation techniques opened new vistas in polymer chemistry. The leading authorities in this field and its pioneers contributed chapters to this collective volume. The controlled polymerisation techniques have enabled preparation of polymers, copolymers, and block copolymers with predetermined molecular weights and narrow polydispersity, in which functional groups or biologically active molecules could be placed at well defined locations. They have also enabled preparation of advanced polymeric structures with precisely determined architectures and improved properties. Moreover, they have provided opportunities for preparation of novel polymeric materials from monomers, which before have not been suitable or accessible for such purposes. Properties of some of these polymeric materials may be significantly different from those of the existing ones. They provide opportunities for new applications. Several patents have already been approved for such speciality applications as, drug delivery, biocompatible surfaces, thermoplastic elastomers, moisture curable sealants, and so on. Many more products, based on polymers fabricated by the living/ controlled polymerisation techniques, will certainly emerge in such specialised areas as, nanotechnology, medical devices, smart polymers, sensors , smart separation technologies, optical fibres and other optical applications, various biomaterials, etc.