COMPLEXES OF PLATINUM(II) WITH 2,2'-BIPYRIMIDINE - EFFECT OF HYDROGEN-BONDING ON INTERMETALLIC INTERACTIONS
COMPLEXES OF PLATINUM(II) WITH 2,2'-BIPYRIMIDINE - EFFECT OF HYDROGEN-BONDING ON INTERMETALLIC INTERACTIONS
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DOI：
10.1039/dt9780001127
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发表时间：
1978-01-01
期刊：
影响因子：
--
通讯作者：
LUDI, A
中科院分区：
文献类型：
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作者：
KIERNAN, PM;LUDI, A
合成并表征了2，2 ′-联嘧啶与铂（II）的配合物[PtX_2（bipym）]（X = CN、Cl或SCN; X_2 = C_2 O_4）、[Pt（bipym）_2]-[PtX_4]（X = Cl或CN）和[Pt_2（NH_3）_4（bipym）][NO_3]_4。在可见光区的强吸收带分配给金属-金属相互作用涉及到强氢键的非配位杂环氮原子。
Platinum(II) complexes with 2,2′-bipyrimidine, [PtX2(bipym)](X = CN, Cl, or SCN; X2= C2O4), [Pt(bipym)2]-[PtX4](X = Cl or CN), and [Pt2(NH3)4(bipym)][NO3]4, have been synthesised and characterised. Intense absorption bands in the visible region assigned to metal–metal interactions are related to strong hydrogen bonding involving the unco-ordinated heterocyclic nitrogen atoms.