Copper, Uranium and REE Mineralisation in an Exhumed Oil Reservoir, Southwest Orkney, Scotland

Copper, Uranium and REE Mineralisation in an Exhumed Oil Reservoir, Southwest Orkney, Scotland
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DOI:
10.3390/geosciences13050151
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发表时间:
2023-05
期刊:
影响因子:
2.7
通讯作者:
E. Heptinstall;J. Parnell;J. Armstrong;A. Schito;T. O. Akinsanpe
E. Heptinstall;J. Parnell;J. Armstrong;A. Schito;T. O. Akinsanpe
中科院分区:
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文献类型:
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作者:
E. Heptinstall;J. Parnell;J. Armstrong;A. Schito;T. O. Akinsanpe

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铜、铀和稀土元素(REE)矿化产于苏格兰奥克尼西南部含油气的泥盆纪陆相砂岩中。风成Yesnaby砂岩组和河流相Harra Ebb砂岩组是石油侵位后的矿化产物。富含稀土的APS矿物闪长岩尤其与沥青结核共生,其中许多结核含有褐铜矿。随后,热液铜和其他硫化物以及重晶石在~190°C的温度下进一步矿化了油藏。随着石炭-二叠纪的隆升,石油的生物降解发生在晚些时候。该产出证实了沉积盆地中温度相对较低的铜-APS成矿作用是可能的。
Copper, uranium, and rare earth element (REE) mineralisation occurs in hydrocarbon-bearing Devonian continental sandstones in southwest Orkney, Scotland. The aeolian Yesnaby Sandstone Formation and fluvial Harra Ebb Sandstone Formation were mineralised following oil emplacement. The REE-bearing APS mineral florencite is particularly associated with bituminous nodules, many of which contain brannerite. Subsequently hydrothermal copper and other sulphides, and barite, further mineralised the oil reservoir at a temperature of ~190 °C. Oil was mobilised through mineralised fractures at this stage. Biodegradation of the oil occurred later, following the Carboniferous-Permian uplift. The occurrence confirms that Cu-APS mineralisation is possible in relatively low-temperature regimes in sedimentary basins.