Post-modification of the interior of porous shape-persistent organic cage compounds.

Post-modification of the interior of porous shape-persistent organic cage compounds.
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DOI:
10.1002/anie.201208156
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发表时间:
2013-03
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影响因子:
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通讯作者:
Markus W Schneider;Iris M. Oppel;A. Griffin;M. Mastalerz
Markus W Schneider;Iris M. Oppel;A. Griffin;M. Mastalerz
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文献类型:
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作者:
Markus W Schneider;Iris M. Oppel;A. Griffin;M. Mastalerz

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内部装饰:后合成方法允许制备具有功能化内部空腔的多孔有机笼状化合物。该方法以定量产率产生改性笼状化合物,并打开了制备具有不同功能的有机合金的可能性。基于溶液的技术显示了溶解性的优势,这是由离散有机分子衍生的多孔材料的固有特性。
Interior decorating: A post‐synthetic method allows porous organic cage compounds to be prepared with functionalized interior cavities. The approach produces modified cage compounds in quantitative yield and opens the possibility of preparing organic alloys with different functionality. The solution‐based technique shows the advantage of solubility, an inherent property of porous materials derived from discrete organic molecules.