Back Cover: A Structurally Characterized Cobalt(I) s-Alkane Complex (Angew. Chem. Int. Ed. 15/2020)
Back Cover: A Structurally Characterized Cobalt(I) s-Alkane Complex (Angew. Chem. Int. Ed. 15/2020)
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封底：结构表征的钴(I) s-烷烃络合物（Angew. Chem. Int. Ed. 15/2020）
DOI：
10.1002/anie.202002162
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发表时间：
2020
期刊：
影响因子：
--
通讯作者：
Boyd T
中科院分区：
文献类型：
--
作者：
Boyd T
.如SA Macgregor、AS Weller等人在其通讯第6177页中所述，通过从降冰片二烯前体进行单晶到单晶固体/气体氢化来合成钴双烷s-烷烃络合物。封面图片显示标题钴σ-烷烃配合物在其阴离子笼中，突出显示货车德瓦尔斯表面。由阴离子笼提供的非共价相互作用对于这种显着的复合物的稳定是必不可少的。
. A cobalt norbornane s-alkane complex…… was synthesized by a single-crystal to single-crystal solid/gas hydrogenation from a norbornadiene precursor, as described by SA Macgregor, AS Weller et al. in their Communication on page 6177. The cover picture shows the title cobalt σ-alkane complex within its anion cage, with the van der Waals surface highlighted. The non-covalent interactions provided by the anion cage are essential for the stabilization of this remarkable complex.