REGIOSELECTIVE AND STEREOSELECTIVE CROSS-COUPLING REACTION OF OPTICALLY-ACTIVE ALLYLSILANES - STEREOCONTROL OF PALLADIUM-MEDIATED S-E' REACTIONS
REGIOSELECTIVE AND STEREOSELECTIVE CROSS-COUPLING REACTION OF OPTICALLY-ACTIVE ALLYLSILANES - STEREOCONTROL OF PALLADIUM-MEDIATED S-E' REACTIONS
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DOI：
10.1016/0040-4039(94)88043-3
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发表时间：
1994-02-21
影响因子：
1.8
通讯作者：
HIYAMA, T
中科院分区：
文献类型：
--
作者：
HATANAKA, Y;GODA, K;HIYAMA, T
光学活性的烯丙基硅烷在钯催化剂和氟化物盐的存在下与芳基三氟甲磺酸酯进行γ-区域选择性交叉偶联反应;偶联产物的绝对构型和% ee可以通过选择氟化物盐和溶剂的极性来控制。
Optically active allylsilanes undergo the gamma-regioselective cross-coupling reactions with aryl triflates in the presence of a palladium catalyst and a fluoride salt; the absolute configuration and % ee of the coupled products could be controlled by the choice of the fluoride salt and the polarity of the solvent.