Wave packet dynamics in triplet states of Na2 attached to helium Nanodroplets

Wave packet dynamics in triplet states of Na2 attached to helium Nanodroplets
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DOI:
10.1021/jp070893i
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发表时间:
2007-08-09
影响因子:
2.9
通讯作者:
Stienkemeier, Frank
Stienkemeier, Frank
中科院分区:
化学3区
文献类型:
--
作者:
Claas, Patrick;Droppelmann, Georg;Stienkemeier, Frank

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利用氦纳米液滴分离(HENDI)技术结合飞秒泵浦-探测光谱,研究了Na-2二聚体在三重态基态和激发态激发的振动波包动力学.在所采用的共振多光子电离方案的不同途径进行了鉴定。在该方法的精度范围内,波包动力学似乎不受氦滴环境的干扰。
The dynamics of vibrational wave packets excited in Na-2 dimers in the triplet ground and excited states is investigated by means of helium nanodroplet isolation (HENDI) combined with femtosecond pump-probe spectroscopy. Different pathways in the employed resonant multiphoton ionization scheme are identified. Within the precision of the method, the wave packet dynamics appears to be unperturbed by the helium droplet environment.