Glutamic acid dendrimers attached to a central ferrocene core: Synthesis and properties
Glutamic acid dendrimers attached to a central ferrocene core: Synthesis and properties
复制标题
DOI：
10.1021/ma050531d
复制
发表时间：
2005-09-06
期刊：
影响因子：
5.5
通讯作者：
Kraatz, HB
中科院分区：
文献类型：
--
作者：
Appoh, FE;Thomas, DS;Kraatz, HB
描述了一系列具有中心二茂铁核的基于谷氨酸的树枝状大分子的首次合成。通过光谱学对这些材料进行了全面表征，并且显示出强烈的分子内氢键。这种氢键可被二甲基亚砜破坏。核心的氧化还原性质因肽树枝状球的增加而减弱。但即使在第6代，外部与氧化还原核心之间也存在相互作用。
The first synthesis of a series of glutamic acid based dendrimers having a central ferrocene core is described. The materials were fully characterized spectroscopically and display strong intramolecular H-bonding. This H-bonding can be disrupted with DMSO. The redox properties of the core are attenuated by the increase in the peptide dendritic sphere. But even at generation 6, there is communication between the exterior and the redox core.