Synthesis and Photophysical Properties of λ5-Phosphinines as a Tunable Fluorophore
Synthesis and Photophysical Properties of λ5-Phosphinines as a Tunable Fluorophore
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DOI：
10.1021/jacs.7b13018
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发表时间：
2018-02-14
影响因子：
15
通讯作者：
Hayashi, Minoru
中科院分区：
文献类型：
--
作者：
Hashimoto, Naoki;Umano, Rika;Hayashi, Minoru
本文报道了一系列在溶液和固体状态下都显示出明显荧光的λ（5）-膦配体的合成。C4-选择性亲电取代和随后的转化实现了一个容易的制备范围广泛的衍生物hiving多个取代基的电子修饰，这提供了潜在的微调的物理化学性质。
A practical synthesis of a variety of lambda(5)-phosphinines, which show distinct fluorescence both in solution and solid state; is described. Both C4-selective electrophilic substitutions and the following conversions realized an easy preparation of a wide range of derivatives hiving several substituents for electronic modification, which provides the potential for fine-tuning of the photophysical properties.