Cyclic Voltammetry of Neptunium in Different Media

Cyclic Voltammetry of Neptunium in Different Media
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镎在不同介质中的循环伏安法

DOI:
10.1080/10256018208544731
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发表时间:
1982
影响因子:
1.3
通讯作者:
J. Večerník
J. Večerník
中科院分区:
环境科学与生态学4区
文献类型:
--
作者:
U. Niese;J. Večerník

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在HClO_4和HNO_3溶液中,由于Np ~(4+)只发生一次单电子电荷转移,故可与Np ~(4+)在玻碳电极上同时测定。在醋酸缓冲介质和硫酸介质中,测定可能在玻碳电极上进行,但在Np ~(4+)存在下,我们发现Np ~(4+)与Np ~(4+)之间存在相互作用。考虑到这种影响,确定是可能的。
can be determined simultancously with Np4+ at the glassy carbon electrode in HClO4 and HNO3 solutions, because there is only one monoelectronic change transfer for . In acetate buffer medium and in sulfuric acid the determination of possible at the glassy carbon electrode, but in presence of Np4+ we found out an interaction between and Np4+. Considering this effect the determination of is possible.