Planar chiral cyclic ether: asymmetric resolution and chirality transformation.
Planar chiral cyclic ether: asymmetric resolution and chirality transformation.
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DOI：
10.1021/ja053347g
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发表时间：
2005-08
影响因子：
15
通讯作者：
K. Tomooka;Nobuyuki Komine;D. Fujiki;T. Nakai;Syun-ichi Yanagitsuru
中科院分区：
文献类型：
--
作者：
K. Tomooka;Nobuyuki Komine;D. Fujiki;T. Nakai;Syun-ichi Yanagitsuru
在一个九元二烯丙基环醚中发现了非常稳定的平面手性。通过动力学拆分一种外消旋醚来制备对映体富集的醚，这是一种有价值的新型手性结构单元。
Remarkably stable planar chirality was found in a nine-membered diallylic cyclic ether. Enantiomerically enriched ether was prepared by a kinetic resolution of a racemic one, which is valuable as a novel type of chiral building block.