Silylene‐Induced Reduction of [Mn2(CO)10]: Formation of a Five‐Coordinate Silicon(IV) Complex with an O‐Bound [(OC)4Mn=Mn(CO)4]2– Ligand
Silylene‐Induced Reduction of [Mn2(CO)10]: Formation of a Five‐Coordinate Silicon(IV) Complex with an O‐Bound [(OC)4Mn=Mn(CO)4]2– Ligand
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DOI：
10.1002/ejic.201600913
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发表时间：
2017-01
影响因子：
2.3
通讯作者：
Johannes A. Baus;Jordi Poater;F. Bickelhaupt;R. Tacke
中科院分区：
文献类型：
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作者：
Johannes A. Baus;Jordi Poater;F. Bickelhaupt;R. Tacke
施主稳定的硅烯[iPrNC(NiPr2)NIPR]2Si(1)与[Mn2(CO)10]反应生成了五配位的硅(IV)配合物6，同时消除了两个CO分子。在这个氧化还原反应中，二锰碎片被还原成与硅(IV)物种{[iPrNC(NiPr2)NIPR]2Si}2+配位的[(OC)4Mn=Mn(CO)4]2-部分。
Treatment of the donor-stabilized silylene [iPrNC(NiPr2)NiPr]2Si (1) with [Mn2(CO)10] leads to the five-coordinate silicon(IV) complex 6, accompanied by elimination of two CO molecules. In this redox reaction, the dimanganese fragment is reduced to form an [(OC)4Mn=Mn(CO)4]2– moiety that is coordinated to the silicon(IV) species {[iPrNC(NiPr2)NiPr]2Si}2+.